Could tyrosine and tryptophan serve multiple roles in biological redox processes?
نویسندگان
چکیده
منابع مشابه
Could tyrosine and tryptophan serve multiple roles in biological redox processes?
Single-step electron tunnelling reactions can transport charges over distances of 15-20 Åin proteins. Longer-range transfer requires multi-step tunnelling processes along redox chains, often referred to as hopping. Long-range hopping via oxidized radicals of tryptophan and tyrosine, which has been identified in several natural enzymes, has been demonstrated in artificial constructs of the blue ...
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ژورنال
عنوان ژورنال: Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
سال: 2015
ISSN: 1364-503X,1471-2962
DOI: 10.1098/rsta.2014.0178